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Learn more Check out. Abstract Kinetic study has been performed to understand the reactivity of novel cationic gemini surfactants viz. Citing Literature. Supporting Information Supporting information may be found in the online version of this article. Volume 26 , Issue 8 August Pages Related Information.

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Close Figure Viewer. Browse All Figures Return to Figure. Previous Figure Next Figure. Int J Pharm — Friedman F Applications of the ninhydrin reaction for analysis of amino acids peptides, and proteins to agricultural and biomedical sciences. Syntheses and applications. Tetrahedron — J Dispers Sci Technol — J Surf Sci Technol — J Colloid Interace Sci — El-Sadek BM Synthesis of selected gemini surfactants: surface, biological activity, and corrosion efficiency against hydrochloric medium. Der Chemica Sin — Singh V, Tyagi R Steady-state fluorescence investigations of aqueous binary mixtures of myristyl alcohol based bissulfosuccinate anionic gemini surfactant and effect of different conventional surfactants therein.

J Dispers Sci Technol Colloid J — Small angle neutron scattering and fluorescence studies. J Phys Chem — Nature — PubMed. McCaldin DJ The chemistry of ninhydrin.

Chem Rev — A spectrophotometric study of hydrindantin reactions. J Biol Chem —22 PubMed.

Micellar Catalysis

Kabir-ud-Din BM, Khan IA Kinetics and mechanism of the ninhydrin reaction with dl-methionine in the absence and presence of organic solvents. Ind J Chem B — Kabir-ud-Din FW, Khan Z Micelle-catalyzed reaction of ninhydrin with dl-valine in the absence and presence of organic solvents. Int J Chem Kinet — Ind J Chem A — Otsuka Y, Ito A, Takeuchi M, Tanaka H Effect of amino acid on calcium phosphate phase transformation: attenuated total reflectance-infrared spectroscopy and chemometrics.

Effect of the spacer chain length on the critical micelle concentration and micelle ionization degree. Langmuir — These spectra are consistent with the structure of formyl stearyl alcohols. Formyl proton of the product has two groups of chemical shift with multiplet. The analysis showed that this product was mixture of formyl stearyl alcohol bearing formyl moiety at the end of long chain and those bearing formyl moiety among the long chain. Ratio of intensities of the two formyl protons was 0.

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This means that internal double bond of oleyl alcohol was transferred to the end of the long chain by isomerization during the hydroformylation. Accordingly it was reasonable that the catalyst showed good activity in the isomerization of the oleyl alcohol. Yield of formyl stearyl alcohol was At above this temperature, decrease of yield was observed.

It may be owe to the decomposition of the catalyst. In addition, higher temperature promoted the competitive hydrogenation of oleyl alcohol, which can be regard as one of the reasons for the decrease of selectivity of the reaction.

Multicomponent Reactions Accelerated by Aqueous Micelles

Meanwhile from Fig. From Fig. The results indicated that the catalyst was recoverable. Yield of aldehyde decreased in the fourth run. The in situ formed catalyst was easily separated from the reaction mixture and Fig. References [1] M. Beller, B.

Introduction to Surfactants

Cornils, C. Frohning, C. Kohlpaintner, J. A Cornils, W. Ruhrchemie, H. Bahrmann, B. Cornils, DE 3,, ; b A. Cornils, DE 3,, Russel, Platinum. Jin, Y. Yan, H.

  • Khan M.N. Surfactant Science Series. Volume Micellar Catalysis [PDF] - Все для студента.
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Zuo, B. Fell, J. Jin, X. Zheng, B. A: Chem. Zheng, J. Jiang, X.